Preheat oven to 375 degrees Fahrenheit. Lightly spray a cooking sheet with non-stick cooking spray.
Mix the flour and baking soda in a small bowl and set aside.
Mix peanut butter, butter, and brown sugar in a medium bowl with a spoon until smooth.
Add the egg and the vanilla; beat until smooth.
Add the flour mixture and stir until combined.
Roll the dough into 1-inch balls and place on cookie sheet.
Bake 8-10 minutes.
Remove from oven and allow to cool for 10 minutes - then place in refrigerator and allow to cool fully for another 20 minutes.
FOR THE FILLING
In a microwave-safe bowl heat chocolate chips and butter for about 1 minutes; just until melted. Allow the mixture to sit for about 30 minutes or until slightly stiff.
Heat the marshmallow cream in a microwave for 10 seconds to soften.
Spread marshmallow on a cookie, chocolate on another and sandwich together.
Store cookies in a covered container in the fridge.
Notes
These are even more wonderful warmed in the microwave slightly before eating!